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Synthesis and characterization of poly(1-benzoylsemicarbazide) and poly(1,3,4-oxadiazole amine) from 2-(p-aminophenyl)-1,3,4-oxadizolin-5-one via ring-opening

✍ Scribed by Yasuo Saegusa; Yasuhiro Ozeki; Shigeo Nakamura

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
312 KB
Volume
17
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

A novel thermally stable and semiconducting polyheterocycle, poly(1,3,4‐oxadiazole amine), was synthesized from 2‐(p‐aminophenyl)‐1,3,4‐oxadiazolin‐5‐one via ring‐opening. The polymer is a new class of ordered alternating copoly(aniline) containing 1,3,4‐oxadiazole heterocyclic units. The polymer is highly thermally stable and exhibits no weight loss up to 370°C in air. Its electric conductivity is less than 10^−10^ S · cm^−1^ at ambient temperature, but markedly increases to 6,5 · 10^−7^ S · cm^−1^ upon doping with iodine.

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