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Synthesis and characterization of oxime-bearing hexakis(2-formylphenoxy)-phosphazene and its derivatives

✍ Scribed by Orhan Pamukçi; Erol Çil; Saliha Begeç; Mustafa Arslan

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
150 KB
Volume
18
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

Hexakis(2‐formylphenoxy)cyclotri‐phosphazene (2) was obtained from the reaction of hexachlorocylotriphosphazene (1) with 2‐hydroxy‐benzaldehyde. Hexakis(2‐[(hydroxyimino)methyl]‐phenoxy)cyclotriphosphazene (3) was synthesized from the reaction of 2 with hydroxlaminehydrochloride in pyridine. Hexasubstituted compounds 4, 5, 6, 8, 9, and 10 were obtained from the reactions of 3 with methyl iodide, ethyl bromide, allyl bromide, propanoyl chloride, benzoyl chloride, and 4‐methoxybenzoyl chloride, respectively. Disubstituted product 7 was obtained from the reaction of 3 with chloroacetyl chloride. Pure and defined products could not be obtained from the reaction of 3 with acetyl chloride, benzyl chloride, and 2‐chlorobenzoyl chloride. The compounds were characterized by elemental analysis and IR, ^1^H, ^13^C, and ^31^P NMR spectroscopy. © 2007 Wiley Periodicals, Inc. Heteroatom Chem 18:791–797, 2007; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20350

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