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Synthesis and Characterization of Organically Templated Metal Arsenates with a Layer Structure: [NH3(CH2)3NH3]0.5[M(OH)AsO4] (M=Ga, Fe)

✍ Scribed by Yue-Chun Liao; Shi-Hao Luo; Sue-Lein Wang; Hsien-Ming Kao; Kwang-Hwa Lii

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 233 KB
Volume: 155
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.2000.8883

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✦ Synopsis

Two organically templated metal arsenates, [NH 3 (CH 2 ) 3 NH 3 ] 0.5 [M(OH)AsO 4 ] (M ‫؍‬ Ga, Fe), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray di4raction and 71 Ga NMR spectroscopy. The two compounds are isostructural and crystallize in the orthorhombic space group Fdd2 (No. 43) with a ‫؍‬ 9.5584(7) A s ,

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