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Synthesis and Characterization of the First Organically Templated Layered Cerium Phosphate Fluoride: [(CH2)2(NH3)2]0.5 [CeIVF3(HPO4)].

✍ Scribed by Ranbo Yu; Dan Wang; Shintaro Ishiwata; Takashi Saito; Masaki Azuma; Mikio Takano; Yunfa Chen; Jinghai Li


Publisher
John Wiley and Sons
Year
2004
Weight
91 KB
Volume
35
Category
Article
ISSN
0931-7597

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A new three-dimensional gallium phosphate, [NH 3 (CH 2 ) 4 NH 3 ] 2 [Ga 4 (HPO 4 ) 2 (PO 4 ) 3 (OH) 3 ] ' yH 2 O (y&5.4), has been synthesized under hydrothermal conditions at 433 K in the presence of 1,4-diaminobutane and its structure determined using room-temperature single-crystal X-ray di4racti