The new metal-free phthalocyanine 2 and phthalocyaninatometals 3-5 (M = Ni, Co and Zn) carrying eight hydroxyethylmercapto groups on peripheral positions have been synthesized from 1,2-bis(hydroxyethylmercapto)-4,5-dicyanobenzene in the presence of a suitable anhydrous metal salt [NiCl 2 , CoCl 2 or
Synthesis and characterization of octakis-(9-anthracenylmethylthio) substituted novel porphyrazines
✍ Scribed by Ergün Gonca
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 291 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0340-4285
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Novel phthalocyanines (M = Ni, Zn, Co) bearing eight 2'-ing anhydrous metal salts [NiC12, Zn(02CMe)2, CoC12]. Comaminophenoxy and 2'-amino phenylsulfanyl substituents on plexation of octakis(2'-amino phenylsulfany1)-substituted peripheral positions have been prepared starting from 4,5-metallo phthal
## Abstract The new α‐aminophosphonic acids are synthesized, reacting (9H‐fluoren‐9‐yl)urea with formaldehyde and phosphorus trichloride. (9H‐Fluoren‐9‐yl)urea was prepared from spiro(fluoren‐9,4′‐imidazolidine)‐2′,5′‐dione by alkaline hydrolysis with Ba(OH)~2~. The structure of the title compounds