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Synthesis and Characterization of Novel Octakis(2′-aminophenoxy and 2′-Aminophenylsulfanyl)-Substituted Metallophthalocyanines

✍ Scribed by Kandaz, Mehmet ;Bekaro.Lu, özer

Publisher
Wiley (John Wiley & Sons)
Year
1997
Tongue
English
Weight
477 KB
Volume
130
Category
Article
ISSN
0009-2940

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✦ Synopsis

Novel phthalocyanines (M = Ni, Zn, Co) bearing eight 2'-ing anhydrous metal salts [NiC12, Zn(02CMe)2, CoC12]. Comaminophenoxy and 2'-amino phenylsulfanyl substituents on plexation of octakis(2'-amino phenylsulfany1)-substituted peripheral positions have been prepared starting from 4,5-metallo phthalocyanines (2b, 3b and 4b) with Pd" to form the bis(2'-aminophenoxy)-1,2-dicyanobenzene or 4,5-bis(2'-ami-pentanuclear product was accomplished from their mixtures. nophenyl sulfany1)-1,2-dicyanobenzene and the correspond-

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