Starting from some new 2,5-disubstituted-1,3,4-oxadiazole difluorides, synthesized by cyclocondensation of dihydrazides with 4-fluorobenzoic acid, novel poly(arylene ether)s were prepared by halo displacement polymerizations with bisphenol A in the presence of potassium carbonate. Model reactions de
✦ LIBER ✦
Synthesis and Characterization of Novel Pyridines and 3,3′-Bridged Bipyridines Using 1,x-Cyclohexanediones
✍ Scribed by Ralf Keuper; Nikolaus Risch
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 280 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-193X
No coin nor oath required. For personal study only.
✦ Synopsis
A one-pot reaction using 1,x-cyclohexanediones, a Mannich 18, 20, and 22. This strategy offers a great flexibility in the design of new building blocks, e.g. in supramolecular base (or its hydrochloride), and ammonium acetate delivers novel pyridines or 3,3Ј-bridged bipyridine compounds 8, 16, chemistry and underlines the efficiency of domino reactions.
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