Synthesis and characterization of novel polyurethanes based on 1,3-bis(hydroxymethyl) benzimidazolin-2-one and 1,3-bis(hydroxymethyl) benzimidazolin-2-thione hard segments
β Scribed by A. V. Raghu; G. S. Gadaginamath; Tejraj M. Aminabhavi
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 161 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0021-8995
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## Abstract Eight novel polyurethanes based on 2,2β²β[1,4βphenylenebis(nitrilomethylylidene)]diphenol and 2,2β²β[4,4β²βmethyleneβdiβ2βmethylphenyleneβ1,1β²βbis(nitrilomethylylidene)]diphenol acting as hard segments with two aromatic and two aliphatic diisocyanates (4,4β²βdiphenylmethane diisocyanate, to
Hard segment model compounds based on diphenyl methane diisocyanate (MDI) and hydroquinone bis(2-hydroxyethyl) ether (HQE) were synthesized; these models were end-capped with ethanol (E) or 2-phenoxyethanol (F). NMR spectroscopy and GPC analysis confirm the expected structure: R-(MDI-HQE) pΟͺ1 -MDI-R