Synthesis and characterization of novel dendritic poly(ester-amine) with peripheral hydroxyl

✍ Scribed by Dong-Mei Xu; Ke-Da Zhang; Chun-Hua Ning; Xiu-Lin Zhu

• Publisher: John Wiley and Sons
• Year: 2005
• Tongue: English
• Weight: 84 KB
• Volume: 97
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.21730

✦ Synopsis

Abstract

Dendritic poly(ester‐amine) with a peripheral hydroxyl [PEA(OH)] was synthesized from dendritic PEA terminated with acrylic double bonds [PEA()] and diethanolamine (DEA) by a Michael addition reaction. The effects of the reaction temperature, time, and solvent on the purities of PEA(OH) were studied. It was found that when the mole ratio of PEA() to DEA was 1:8 and the reaction was carried out in methanol at 25°C for 22 h, the purity of PEA(OH) was 94.6%. The structure of PEA(OH) was identified by IR, ^1^H‐NMR, and elemental analysis. PEA(OH) is a surfactant and its aqueous form exhibits cloud points between the mass concentrations of 0.1 and 50 mass %. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 60–64, 2005