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Synthesis and characterization of novel chiral NHC–palladium complexes and their application in copper-free Sonogashira reactions

✍ Scribed by Yang, Longguang; Guan, Pei; He, Pan; Chen, Qian; Cao, Changsheng; Peng, Yu; Shi, Zhan; Pang, Guangsheng; Shi, Yanhui


Book ID
120177512
Publisher
Royal Society of Chemistry
Year
2012
Tongue
English
Weight
296 KB
Volume
41
Category
Article
ISSN
1477-9226

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## Abstract A new palladium-bidentate complex [m-C6H4(CH2ImMe)2(PdCl2)] (III) was prepared in two steps. In the first step, [m-C6H4(CH2ImMeAgCl)2] (II) (Im = imidazole moiety) was obtained by reacting imidazolium salt [m-C6H4(CH2ImMe)2]Cl2 (I) (prepared by quaternisation of Nmethylimidazole with 1,