Synthesis and characterization of new soluble polyamides containing ether and pendant cyclododecylidene groups
β Scribed by Der-Jang Liaw; Been-Yang Liaw
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 298 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1042-7147
No coin nor oath required. For personal study only.
β¦ Synopsis
A series of new soluble polyamides having flexible ether and bulky pendant cyclododecylidene groups in the polymer chain were prepared by the direct polycondensation of 1,1-bis(4-(4-aminophenoxy)phenyl)cyclododecane (BAPCD) and various aromatic dicarboxylic acids in Nmethyl-2-pyrrolidinone (NMP) using triphenyl phosphite and pyridine as condensing agents. Polymers having inherent viscosities of 0.74Β±1.00 dl/g were produced in high yield. Almost all the polymers could be readily dissolved in polar solvents such as NMP, dimethylsulfoxide, N,N-dimethylacetamide, N, N-dimethylformamide, m-cresol, pyridine and tetrahydrofuran. Most of the polymers could be solution-cast into transparent, flexible, tough films which were further characterized by X-ray and mechanical analysis. X-ray diffractograms of polyamides indicated all polymers were amorphous except the polymer derived from rigid diacid such as 4,4'-biphenyldicarboxylic acid. Most of the polymers revealed a distinct glass transition on the differential scanning calorimetry traces in the range of 234Β±273 Β°C. Thermogravimetric analysis showed that most of the polymers were stable up to 400Β°C in nitrogen atmosphere. The polymer films had a tensile strength range of 88Β±147 MPa and high tensile modulus range of 2.8Β±3.5 GPa.
π SIMILAR VOLUMES
The polymerization of bisphenol-A diphthalic anhydride with 2,3-bis(perΒ―uoroalkyl methyl)butane-1,4 diamine (NFD) led to a new series of Β―uorinated poly(ether imide)s. In the case of C 4 F 9 perΒ―uoroalkyl chain, polymers and copolymers obtained from a mixture of m-phenylenediamine and NFD were chara
Poly(arylene ether)s ( 3) containing pendant benzoyl groups were prepared by the aromatic substitution reaction of 2,5-difluoro-4-benzoylbenzophenone ( 2) with hydroquinone (1a) and methylhydroquinone (1b) in the presence of potassium carbonate in N,N-dimethylacetamide. The polycondensation proceede
Novel high glass transition temperature polyaryletherketones, containing pendant amido, alkyl, and carboxyl groups with reduced viscosity above 0.54 dL/g, were synthesized via solution nucleophilic polycondensation reaction of phenolphthalin, 2,2Π-diisopropyl-5,5Π-dimethylphenolphthalin, and 3,3 -bi