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Synthesis and characterization of new copolymers of thiophene and vinylene: Poly(thienylenevinylene)s and poly(terthienylenevinylene)s with thioether side chains

✍ Scribed by Francesca Goldoni; René A. J. Janssen; E.W. Meijer

Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
258 KB
Volume
37
Category
Article
ISSN
0887-624X

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✦ Synopsis

been synthesized. The synthesis starts from the thiophene monomers and trimers, which are formylated to give the corresponding dialdehydes. The dialdehydes are reductively polymerized using a McMurry coupling. The polymers are characterized by GPC, optical spectroscopy (FT-IR, UV-vis, circular dichroism spectroscopy and photoluminescence) and by proton and carbon NMR spectroscopy. The polymers are soluble in common organic solvents, such as THF, chloroform, toluene, benzene and 1,2-dichlorobenzene. The solvatochromism and thermochromism of the polymers in solution are investigated, while the optical activity of the polymers is used to investigate the supramolecular aggregation.

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