✦ LIBER ✦

Synthesis and characterization of new amine-imine ligands based on trans-2,5-disubstituted pyrrolidines

✍ Scribed by James A. Sweet; Jennifer M. Cavallari; William A. Price; Joseph W. Ziller; Dominic V. McGrath

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 258 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(96)00511-3

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✦ Synopsis

We present a modular synthesis of a new class of chiral N,Nchelating ligands containing the C2-symmetric trans-2,5-disubstituted pyrrolidine moiety linked to a pyridine ring. (-)-2-[(2R,5R)-2,5-Dimethylpyrrolidin-l-ylmethyl]pyridine (11, (R,R)-MePMP), (-)-2-[2-((2R,5R)-2,5-dimethylpyrrolidin-l-yl)ethyl]pyridine (12, (R,R)-MePEP), and (+)-2-[(2R,5R)-2,5-diphenylpyrrolidin-l-ylmethyl]pyridine (13, (R,R)-PhPMP) have been prepared. The X-ray structure of the (r/3-allyl)Pd complex of (R,R)-MePMP ( ) is reported.

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