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Synthesis and characterization of neutral and cationic diamino carbene complexes of gold(I)

✍ Scribed by Helgard G. Raubenheimer; Louise Lindeque; Stephanie Cronje

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
693 KB
Volume
511
Category
Article
ISSN
0022-328X

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✍ Claudio Bianchini; Géraldine Lenoble; Werner Oberhauser; Sébastien Parisel; Fabr 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 160 KB

## Abstract The __ortho__‐palladation of the iminophosphane ligand 6‐phenyl‐2‐[(2,6‐diisopropylphenyl)imino]pyridine (HL) with Pd(OAc)~2~ and PdCl~2~(PhCN)~2~ in benzene yields the neutral Pd–C,N,N pincer complexes Pd(OAc)(κ^3^‐C,N,N‐L) (1) and PdCl(κ^3^‐C,N,N‐L) (2), respectively. In the presence