Synthesis and characterization of monomeric siloxo palladium(II) complexes: crystal structure of [Pd(tmeda)(C6F5)(OSiPh3)]
✍ Scribed by José Ruiz; Consuelo Vicente; Venancio Rodrı́guez; Natalia Cutillas; Gregorio López; Carmen Ramı́rez de Arellano
- Book ID
- 108187827
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 204 KB
- Volume
- 689
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The reaction of LiN(SiMe~3~)~2~ with two equivalents of 2‐, 3‐, or 4‐cyanopyridine followed by the addition of half an equivalent of [PdCl~2~(PhCN)~2~] gives neutral 1,3,5‐triazapentadienato complexes of the general formula [Pd{HNC(Py)NC(Py)NH}~2~] (Py = 2‐pyridyl 1, 3‐pyridyl 2, 4‐pyri
The compound cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] has been used as the between [(C 6 F 5 ) 2 Ni(&µ-X) 2 Ni-(C 6 F 5 ) 2 ] 2-and L. The treatment of cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] with [M(SAr) 2 (dppe)] leads to the starting material for the preparation of the bimetallic complexes ethane], and the Pt). Th