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Synthesis and characterization of monomeric and polymeric pyridinylimine-based Ni(II) complexes and their catalytic activities in ethylene oligomerization

✍ Scribed by Tansir Ahamad; Saad M Alshehri


Book ID
112174644
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
304 KB
Volume
61
Category
Article
ISSN
0959-8103

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Five new hetero-bimetallic metallocene complexes were synthesized by the reaction of RCpTiCl 3 and a Si-bridged zirconocene complex in refluxing toluene. They were all well characterized. These complexes activated with methylaluminoxane (MAO) are highly active catalysts for the polymerization of eth