Preparation and characterization of acylhydrazone nickel(II) complexes and their catalytic behavior in vinyl polymerization of norbornene and oligomerization of ethylene
โ Scribed by Junxian Hou; Wen-Hua Sun; Dongheng Zhang; Liyi Chen; Wei Li; Dongfeng Zhao; Haibin Song
- Book ID
- 108211466
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 310 KB
- Volume
- 231
- Category
- Article
- ISSN
- 1381-1169
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๐ SIMILAR VOLUMES
## Abstract The polymerization of norbornene (NBE) was investigated in the presence of two novel pyrazolylimine nickel complexes [2โ(C~3~HN~2~Me~2~โ3,5){C(Ph)๏ฃพ[4โR~2~C~6~H~2~(R~1~)~2~โ2,6]}NiBr~2~ (complex 1, R~1~ = ^i^Pr and R~2~ = H; complex 2, R~1~ = H and R~2~ = NO~2~)] activated by methylalumi
A new diphosphinoamine ligand [Ph 2 PN(p-C 6 H 4 OMe)PPh 2 ] was prepared through aminolysis reaction of p-methoxyaniline with Ph 2 PCl in the presence of NEt 3 . Consequently, the corresponding nickel (II) diphosphinoamine complex [(p-C 6 H 4 OMe)N(PPh 2 ) 2 NiCl 2 ] was synthesized and characteriz