Synthesis and characterization of Mn-bearing ilvaite CaFe2−x2+MnxFe3+[Si2O7/O/(OH)]
✍ Scribed by B. Ghazi-Bayat; G. Amthauer; E. Hellner
- Publisher
- Springer
- Year
- 1989
- Tongue
- English
- Weight
- 664 KB
- Volume
- 40
- Category
- Article
- ISSN
- 1438-1168
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An in situ high pressure X-ray diffraction study on synthetic pure ilvaite powder has been performed using a diamond anvil cell. A phase transition from monoclinic to orthorhombic (Pbnm) has been observed at 2.25 Gpa, which can be described as a 2-transition.
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A new copper aluminum silicate CuAl 2 Si 2 O 7 (F,OH) 2 (cualsite) was synthesized hydrothermally from SiO 2 and Al 2 O 3 in a mineralizing solution 1 3 Na 3 AlF 6 ؉ 4 9 Al(NO 3 ) 3 ؉ 1 9 Cu(NO 3 ) 2 ؉ 27.8H 2 O at 600°C and 150 MPa. Cualsite grew epitaxially on the pinacoidal plane of the topaz si