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Synthesis and characterization of liquid crystal polycarbosilanes: poly(1-methyl-1-silaethylene), poly(1-methyl-1-silabutane) and poly(1-silabutane) with pendant mesogenic groups

✍ Scribed by Tomasz Ganicz; Włodzimierz Stańczyk; Ewa Białecka-Florjańczyk; Irma Śledzińska


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
667 KB
Volume
37
Category
Article
ISSN
0032-3861

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Synthesis and characterization of isotac
✍ Giovanni Ricci; Lucia Zetta; Lido Porri; Stefano Valdo Meille 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 332 KB

## Abstract 3‐Methyl‐1,3‐pentadiene has been polymerized with the Al(C~2~H~5~)~2~Cl/Nd(OCOC~7~H~15~)~3~/Al[CH~2~CH(CH~3~)~2~]~3~ system to crystalline polymers consisting essentially of cis‐1,4 units (≥80%). NMR examination has shown that the polymers have an isotactic structure. This conclusion wa