Synthesis and Characterization of Iridium(III) Cyclometalated Complexes with Oligonucleotides: Insights into Redox Reactions with DNA
β Scribed by Shao, Fangwei; Elias, Benjamin; Lu, Wei; Barton, Jacqueline K.
- Book ID
- 118749512
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 487 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0020-1669
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## Abstract We report the synthesis, characterisation, photophysical and electrochemical properties of a series of cationic cyclometallated Ir^III^ complexes of general formula [Ir(ppy)~2~(phen)]PF~6~ (ppy=2βphenylpyridine, phen=a substituted phenanthroline). A feature of these complexes is that th
## Abstract A series of cationic diiminoiridium(III) complexes [Ir(ppyβ__N__,__C__)~2~(Lβ__N__,__N__)](PF~6~) has been prepared [Hppy = 2βphenylpyridine; L = 4,4β²β__t__Bu~2~dpbpy (1), 4,4β²βMe~2~dpbpy (2), 4,4β²βMe~2~pbpy (3), 4,4β²βMe~2~bpy (4)] and their photophysical and electrochemical properties