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Synthesis and characterization of dinuclear vanadium(V) oxido peroxido tartrato complexes

✍ Scribed by Jana Gáliková; Jozef Tatiersky; Erik Rakovský; Peter Schwendt

Book ID
106547736
Publisher
Springer
Year
2010
Tongue
English
Weight
249 KB
Volume
35
Category
Article
ISSN
0340-4285

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Pyrazine-Assisted Dimerization of Molybd
Pyrazine-Assisted Dimerization of Molybdenum(V): Synthesis and Structural Characterization of Novel Dinuclear and Tetranuclear Complexes
✍ Barbara Modec; Martin Šala; Rodolphe Clérac 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 743 KB

## Abstract Reactions of pyrazine (Pyz = C~4~H~4~N~2~) with [MoOCl~4~(H~2~O)]^–^ or [MoOBr~4~]^–^ afforded a series of complexes, dinuclear [(MoOX~4~)~2~(Pyz)]^2–^ (X = Cl, Br), [{MoOCl~3~(Pyz)}~2~O]^2–^ and tetranuclear [(Mo~2~O~4~Cl~4~)~2~(Pyz)~2~]^4–^ anions, with N‐donor ligands engaged either