Synthesis and characterization of tantalum(V) dicarbollide complexes
β Scribed by Uhrhammer, Roger; Crowther, Donna J.; Olson, Jeffrey D.; Swenson, Dale C.; Jordan, Richard F.
- Book ID
- 111906434
- Publisher
- American Chemical Society
- Year
- 1992
- Tongue
- English
- Weight
- 929 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0276-7333
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## The reactions of niobium and tantalum pentachlorides and oxotrichlorobis(triphenylphosphine oxide)niobium(V) with N-arylsalicylaldimines, abbreviated as (Sal-R)H, have yielded new niobium(V) and tantalum(V) complexes of the following three types: (1) MCl,(OR'),[(Sal-R)H]; ( 2){M(NCS),(OC,H,) 2
This review covers the literature about niobium(V) and tantalum(V) complexes containing at least one peroxo ligand in their coordination sphere. In addition to the synthesis aspects, the available structural data as well as several results issued from techniques like IR and Raman spectroscopies, NMR