Synthesis and Characterization of Cationic Square-Planar Iridium(I) Complexes Containing Chiral Diphosphines
β Scribed by Morandini, Franco; Pilloni, Giuseppe; Consiglio, Giambattista; Mezzetti, Antonio
- Book ID
- 126468584
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 576 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0276-7333
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π SIMILAR VOLUMES
The two dinuclear Ir I complexes [Ir 2 (m-Cl) ) smoothly react with 4 equiv. of the lithium salt of aniline to afford the new bis(anilido)iridate(I) ( bis(benzenaminato)iridate(1-)) complexes Li[Ir(NHPh) 2 {(R)-(S)-PPF-PPh 2 }] (4) and Li[Ir(NHPh) 2 {(R)-binap}] (5), respectively. The anionic compl
## Abstract The rhodium(I) complexes __trans__β[Rh(diphos)(CO)Cl] **7** (diphos=pbpb), **8** (diphos=nbpb), and **9** (diphos=cbpb) were synthesized (__Schemeβ 4__) and used as catalysts for the carbonylation of MeOH to AcOH (__Schemeβ 1__). The __trans__ coordination imposed by the rigid Cβspacer fr
## Abstract For Abstract see ChemInform Abstract in Full Text.