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Synthesis and Characterization of Cationic Palladium (6,6‘-Dimethoxybiphenyl-2,2‘-diyl)bis(diphenylphosphine) Complexes

✍ Scribed by Sperrle, Martin; Gramlich, Volker; Consiglio, Giambattista

Book ID: 111672512
Publisher: American Chemical Society
Year: 1996
Tongue: English
Weight: 168 KB
Volume: 15
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om960445p

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Synthesis and Application of Cationic 2,6-Bis(2-oxazolinyl) phenylpalladium(II) Complexes. -A series of cationic Pd(II)-complexes are synthesized, which markedly increase the rate of Diels-Alder reactions (→ (III)/(IV)), Michael additions (→ (VII)) and aldol reactions (→ (X)/( XI)). -