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Synthesis and characterization of binuclear palladium complexes of isocyanides with novel bridging η3-indenyl ligands. Crytal structure of [Pd2(μ-η3-indenyl)2(RNC)2] (R = 2,6-dimethylphenyl)

✍ Scribed by Tomoaki Tanase; Takahito Nomura; Yasuhiro Yamamoto; Kimiko Kobayashi

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
271 KB
Volume
410
Category
Article
ISSN
0022-328X

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## Abstract Reaction of the side‐on end‐on dinitrogen complex [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐N~2~)] (1; in which NPN=(PhNSiMe~2~CH~2~)~2~PPh), with the Lewis acids XR~3~ results in the adducts [{(NPN)Ta}~2~(μ‐H)~2~(μ‐η^1^:η^2^‐NNXR~3~)], XR~3~=GaMe~3~ (2), AlMe~3~ (3), and B(C~6~F~5~)~3~ (4). Th