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Synthesis and Characterization of Alkali Metal and Thallium Polyfluoroantimonates, ASbnF5n+1 (n = 2, 3).

✍ Scribed by Primoz Benkic; H. Donald Brooke Jenkins; Maja Ponikvar; Zoran Mazej


Publisher
John Wiley and Sons
Year
2006
Weight
11 KB
Volume
37
Category
Article
ISSN
0931-7597

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Synthesis and Characterisation of Alkali
✍ PrimoΕΎ Benkič; H. Donald Brooke Jenkins; Maja Ponikvar; Zoran Mazej πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 211 KB

## Abstract Reactions of AF (A = K, Rb, Tl) with excess liquid SbF~5~ in anhydrous HF (or SO~2~) at room temperature give products having the composition ASb~2~F~11~. The reaction between CsF and a small excess of SbF~5~ in anhydrous HF (0.76 mmol of CsF + 4.19 mmol of SbF~5~ in 4 mL of aHF) yields