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Synthesis and Characterization of a Series of New Asymmetric Salphen Mono- and Binuclear Metal Complexes

✍ Scribed by Jiayuan Li; Liqin Guo; Wenjuan Ruan; Zhiang Zhu

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 96 KB
Volume: 28
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.201090175

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## Abstract TiCl~2~[salphen(di‐__t__Bu)] was synthesized, characterized and employed as pre‐catalyst in ethylene homo‐ and copolymerization with propylene, 1‐octene and 10‐undecen‐1‐ol. X‐ray diffraction study on the titanium complex revealed a distorted octahedral coordination of the central metal