Synthesis and Characterization of a Nitroxide−Semiquinone Biradical
✍ Scribed by Shultz, David A.; Farmer, Gary T.
- Book ID
- 115529546
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 134 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
The synthesis and characterization of a biradical in which two ~miquinoue rings a¢ held flgidly co-p~n~r and are a nach.d in a geathml fashion to a carlton-cain double bond is described. The insulin of cyclic voltammeaT and vadable-tempeman¢ EPR studies are fam~eted in terms of the interaction of th
## Abstract A nitroxide biradical 2,6‐dioxy‐2,6‐diaza‐1,1,3,3,5,5,7,7‐octamethyldicyclopentano[__b;e__]pyridine (1) and the corresponding monoradical (2‐oxy‐6‐hydroxy) were prepared starting from 2,2,5,5‐tetramethyl‐3‐oxopyrrolidine by successive condensation with formaldehyde (KOH) or DMF (K in TH