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Synthesis and characterization of a new Mo-Fe-S cluster compound containing MoO3S3 unit and mixed-valent Mo atoms [Et4N]2[Mo2Fe(CO)4(S,O-C6H4-1,2)3Cl2]

โœ Scribed by Bo-Tao Zhuang; An-Jian Lan; Ling-Jie He; Liang-Ren Huang


Book ID
112060274
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
373 KB
Volume
12
Category
Article
ISSN
0256-7660

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Synthesis and Structural Characterizatio
โœ Jin Chen; Shao-Fang Lu; Zi-Xiang Huang; Rong-Min Yu; Qiang-Jin Wu ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 157 KB ๐Ÿ‘ 2 views

Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 ร€ ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 ยดI}{(HgI 3 ) 3 } ยด4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 ยดI} tetramer and (HgI 3 ) ร€ . Compound 1 has been characterized by IR, Raman, UV/Vis, and N