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Synthesis and Characterization of 9(10)-Bromo-9-octadecenoic Acids

✍ Scribed by Amat-Guerri, F. ;Rivas-Palmer, P.

Publisher
John Wiley and Sons
Year
1975
Weight
255 KB
Volume
77
Category
Article
ISSN
0931-5985

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✦ Synopsis

Abstract

9(10)‐Bromo‐cis‐9‐octadecenoic acid, m. p. 36.7° C, was prepared by dehydrobromination of threo‐9,10‐dibromo‐stearic acid with bases and by polar addition of hydrogen bromide to stearolic acid. The trans isomer, m. p. 6°–8° C, was obtained from the corresponding erythro‐dibromide. Both compounds were characterized by IR and NMR spectroscopies and a reaction scheme for their formation by dehydrobromination is suggested.

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