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Synthesis and characterization of 2H-, 3H- and 4H-azepine: the first observation of the thermal distribution equilibrium of azepines

✍ Scribed by Satake, Kyosuke; Okuda, Ryoichi; Hashimoto, Michiaki; Fujiwara, Yasushi; Watadani, Izumi; Okamoto, Hideki; Kimura, Masaru; Morosawa, Shiro


Book ID
115499879
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
248 KB
Volume
17
Category
Article
ISSN
0022-4936

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Swmary: Deprotonation of 2-diethyIumino-5-phenyZ-3!-azepine with strong bases affords a highZy coloured anion, which reacts with deuterim oxide or with an appropriate electrophile to give an azepine bearing the new substituent at C-3. During the last decades several papers have appeared dealing wit