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Synthesis and characterisation of a new helically chiral ruthenium complex

✍ Scribed by Faouzi Aloui; Souad Moussa; Béchir Ben Hassine

Book ID
104098656
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
329 KB
Volume
52
Category
Article
ISSN
0040-4039

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Synthesis and characterisation of a new
Synthesis and characterisation of a new chiral ruthenium picket-fence porphyrin and its use in chiral recognition of racemic isocyanides
✍ Erwan Galardon; Michael Lukas; Paul Le Maux; Gérard Simonneaux 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 205 KB

The preparation of a new chiral porphyrin bearing eight optically active pickets, four on each side of the porphyrin plane is described. Chiral recognition in the complexation of racemic isocyanide to the ruthenium compound leads to the formation of three stereoisomers with low stereoselectivity (15