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Synthesis and Catalytic Epoxidation Activity with TBHP and H 2 O 2 of Dioxo-, Oxoperoxo-, and Oxodiperoxo Molybdenum(VI) and Tungsten(VI) Compounds Containing Monodentate or Bidentate Phosphine Oxide Ligands: Crystal Structures of WCl 2 (O) 2 (OPMePh 2 ) 2 , WCl 2 (O)(O 2 )(OPMePh 2 ) 2 , MoCl 2 (O) 2 dppmO 2 ·C 4 H 10 O, WCl 2 (O) 2 dppmO 2 , Mo(O)(O 2 ) 2 dppmO 2 , and W(O)(O 2 ) 2 dppmO 2

✍ Scribed by Jimtaisong, Ampa; Luck, Rudy L.


Book ID
120297092
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
217 KB
Volume
45
Category
Article
ISSN
0020-1669

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The crystal structures of three dinuclear diperoxo compounds have been determined from single-crystal X-ray diffraction data. All title compounds crystallize as yellow needle-shaped crystals in the triclinic space group P 1(2). ( 1 where 2-MepyH denotes 2-methylopyridine, crystallize with a = 6.733