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Synthesis and Catalytic Application of Homo-bimetallic Metallocene Complexes as Ethylene Polymerization Catalysts

✍ Scribed by Zuo-Feng Feng; Ji-Ling Huang; Yan-Long Qian; Jun-Quan Sun; Wei Chen

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
322 KB
Volume
20
Category
Article
ISSN
0256-7660

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Three new lanthanide (Ln)-alkylaluminium (Al) bimetallic complexes with the formula [(p-CF,CO,),Ln(p-CF,CHO2)AlR2 2THF], (Ln = Nd, Y, R = i-C4H, (i-Bu); Ln = Eu, R = C2H5(Et); THF = tetrahydrofuran) were synthesized by the reaction of Ln(CF,CO,), (Ln=Nd, Y) with HA1 (i-Bu), and of Eu(CF,CO,), with A