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Synthesis and bioactivity of lincomycin 2-monoesters

✍ Scribed by W. Morozowich; A. A. Sinkula; F. A. Mackellar; C. Lewis

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
316 KB
Volume
62
Category
Article
ISSN
0022-3549

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πŸ“œ SIMILAR VOLUMES

Kinetics of alkaline isomerization and h
Kinetics of alkaline isomerization and hydrolysis of lincomycin monoesters
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In alkaline media the 2-, 3-, and Cmonohexanoates of lincomycin rapidly isomerize, each entering into facile equilibrium with the other two, accompanied by hydrolysis of each species to lincomycin. The concentration-time curves of the three esters and of lincomycin as observed in a single experiment

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## Abstract In search for new antibiotics we replaced the amide moiety of lincomycin **1** by a 1,2,3‐triazole ring. The 1,2,3‐triazoles **10a**–**10k** were obtained as single regioisomers by β€˜click reaction’ of azide **5** with the alkyne **9k**, derived from propyl hygric acid, and the alkyl, ar