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Synthesis and Association Behavior of Butadiyne-Bridged [4 4 ](2,6)Pyridinophane and [4 6 ](2,6)Pyridinophane Derivatives

โœ Scribed by Tobe, Yoshito; Nagano, Atsushi; Kawabata, Kazuya; Sonoda, Motohiro; Naemura, Koichiro

Book ID
125953883
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
132 KB
Volume
2
Category
Article
ISSN
1523-7060

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Synthesis and structural studies of [n](
Synthesis and structural studies of [n](2,4)pyridinophane ring system
โœ Nobuhiro Kanomata; Makoto Nitta ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

The facile synthesis of [n](2,4)pyridinophane ring system (n = 9-6) was accomplished by the reaction of N-(1-phenylvinyl)iminophosphorane with cyclic ~1, H-unsaturated ketones. The chain flipping was studied by 'H NMR spectra at various temperatures.