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Synthesis and Association Behavior of [4.4.4.4.4.4]Metacyclophanedodecayne Derivatives with Interior Binding Groups

✍ Scribed by Yoshito Tobe; Naoto Utsumi; Atsushi Nagano; Koichiro Naemura

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 129 KB
Volume: 37
Category: Article
ISSN: 0044-8249
DOI: 10.1002/(sici)1521-3773(19980518)37:9<1285::aid-anie1285>3.0.co;2-b

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✦ Synopsis

Intriguing association behavior in solution is exhibited by the rigid macrocycle 1. For instance, it reacts with organic cations to give ternary complexes of the composition (1⋅cation)⋅1, and with analogous macrocycles without cyano groups it forms heteroaggregates. R=CO C H .

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