𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and assignment of absolute configuration of enantiomeric dicyclohexylammonium 2-oxo-2-thioxo-1,3,2-oxathiaphospholanes

✍ Scribed by Bożenna Krzyżanowska; Wojciech J. Stec; Michał W. Wieczorek; Jarosław Błaszczyk

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
604 KB
Volume
5
Category
Article
ISSN
1042-7163

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The title compound 2 has been synthesized and its structure has been determined by X‐ray analysis. The following crystal data were found: monoclinic, P2~1~, a = 9.936(4), b = 18.009(3), c = 10.418(3) Å, and β = 107.22(3)°. Two molecules of the compound (two oxathiaphospholane anions and two dicyclohexylammonium cations) are present in the independent part of the unit cell. The absolute configuration at the phosphorus atom is established as R~p~. The ionic character of 2 is discussed. In the crystal lattice of 2, a hydrogen‐bonding system occurs.

📜 SIMILAR VOLUMES

ChemInform Abstract: Synthesis of Oxo an
ChemInform Abstract: Synthesis of Oxo and Thioxo Derivatives of 1,2,4-Triazines.
✍ Yu. S. Andreichikov; S. V. Kol'tsova; I. A. Zhikina; D. D. Nekrasov 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v