## Abstract The four photo‐cleavable ligands 1–4 of the macrobicyclic‐cryptand type have been synthesized by introducing a photo‐sensitive 2‐nitrobenzyl‐ or 4,5‐dimethoxy‐2‐nitrobenzyl‐ether bond into one of the bridges. These compounds are expected to retain the selective binding features of the p
Synthesis and Applications of Cryptands
✍ Scribed by Shobhana K. Menon; Sanjay V. Hirpara; Uma Harikrishnan
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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The novel isomeric phosphite cryptands 2, 3, and 4 could be synthesized by a simple one-pot tripod capping method starting from bisphenol 1 and PCl 3 . The assembling of five components led to the formation of a macrobicyclic structure, which probably requires an appropriate preorganization of the r
## Abstract In order to provide a method for in vivo and in vitro detection of cryptand [2.2.2], tritiated cryptand was synthesized by reduction of appropriate bicyclic diamide with tritiated diborane. As part of this synthesis, tritiated diborane was synthesized by the reaction of tritiated sodium