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Synthesis and antitumour activity of new daunorubicin and adriamycin analogues

✍ Scribed by F. Arcamone; L. Bernardi; B. Patelli; P. Giardino; A. Di Marco; A. M. Casazza; C. Soranzo; G. Pratesi

Book ID
112662061
Publisher
Springer
Year
1978
Tongue
English
Weight
337 KB
Volume
34
Category
Article
ISSN
1420-682X

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Synthesis of daunorubicin-14-14C and adr
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✍ C. Rolland Chen; Mary Tan Fon; Alan N. Fujiwara; David W. Henry; Morris A. Leaff πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 French βš– 275 KB

## Abstract Reaction of adriamycinone with excess ^14^CH~3~Mgl and periodate cleavage of the resulting glycol (5) affords daunomycinone‐14‐^14^C (6). Bromination and hydrolysis of 6 gives adriamycinone‐14‐^14^C (8). Coupling of 6 and the 14‐0‐p‐anisyldiphenyl‐methyl derivative (9) with 1‐chloro‐3‐N