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Synthesis and antiproliferative activity of novel symmetrical alkylthio- and alkylseleno-imidocarbamates

✍ Scribed by Elena Ibáñez; Daniel Plano; María Font; Alfonso Calvo; Celia Prior; Juan Antonio Palop; Carmen Sanmartín

Book ID
108116535
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
530 KB
Volume
46
Category
Article
ISSN
0223-5234

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A general synthesis of optically active
A general synthesis of optically active phosphines, phosphinites and thiophosphinites from alkylthio(alkylseleno)phosphonium salts and tris(dimethylamino)phosphine as a thiophilic agent
✍ J. Omelańczuk; M. Mikołgajczyk 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 249 KB

## Tris(dimethylaminolphosphine was found to be a suitable thiophilic reagent which converts optically active aZkyZthiofaZkyZseZeno!phosphosphonium salts into chiral tertiary phosphines and phosphinites with a high stereosetectivity. The first synthesis of opticaZZy active thiophosphinites from bi