Synthesis and Antimalarial Activity of Cyclic Peroxides, 1,2,4,5,7-Pentoxocanes and 1,2,4,5-Tetroxanes
β Scribed by Kim, Hye-Sook; Shibata, Yasuharu; Wataya, Yusuke; Tsuchiya, Kaoru; Masuyama, Araki; Nojima, Masatomo
- Book ID
- 115444842
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 72 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-2623
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π SIMILAR VOLUMES
## a b s t r a c t A convenient synthesis of new unsymmetrically substituted 1,2,4,5-tetroxanes and novel unsymmetrical alkoxy-substituted 1,2,4,5-tetroxanes starting from primary dihydroperoxides was developed. The structure of some tetroxanes was unambiguously assigned by X-ray crystal analysis
The diperoxide 3,6-diphenyl-1,2,4,5-tetroxane was synthesized and its infrared and Raman spectra were measured. The structural stability and the vibrational spectra of 1,2,4,5-tetroxane and 3,6-diphenyl-1,2,4,5-tetroxane were investigated by the DFT-B3LYP and the ab initio MP2 calculations with the