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Synthesis and Amphiphilic Behavior of N , N ‐Bis‐glucosyl‐1,5‐benzodiazepin‐2,4‐dione

✍ Scribed by Lakhrissi, Brahim; Essassi, El Mokhtar; Massoui, Mohamed; Goethals, Gérard; Lequart, Vincent; Monflier, Eric; Cecchelli, Roméo; Martin, Patrick

Book ID
121473297
Publisher
Taylor and Francis Group
Year
2004
Tongue
English
Weight
192 KB
Volume
23
Category
Article
ISSN
0732-8303

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The unexpected rearrangement of 1,5-benz
The unexpected rearrangement of 1,5-benzodiazepin-2,4-dione to a benzimidazol-2-one derivative during N,N'-diglucosylation
✍ Brahim Lakhrissi; Mohamed Massoui; El Mokhtar Essassi; Vincent Lequart; Nicolas 📂 Article 📅 2004 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 74 KB

## Abstract Reaction of 1,5‐benzodiazepin‐2,4‐dione with 3‐__O__‐substituted‐5,6‐anhydro‐1,2‐isopropylidene‐α‐D‐glucofuranose gave the unexpected __N,N'__‐di‐glucofuranosyl benzimidazol‐2‐one by a novel rearrangement and ring closure reaction. A mechanism is proposed.