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Synthesis and alkali cation extraction ability of 1,3-alt-thiacalix[4]mono(crown) ethers

✍ Scribed by Viktor Csokai; Alajos Grün; Gyula Parlagh; István Bitter

Book ID
104251904
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
166 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

The first representatives of 1,3-alt-thiacalix[4]mono(crown-5 and -6) ethers were synthesized by the cyclocondensation of 25,27-dialkoxythiacalix[4]arenes with tetraethylene glycol ditosylate and 1,14-diiodo-3,6,9,12-tetraoxatetradecane, respectively. The complexing abilities of ligands were determined by the alkali (Li + , Na + , K + , Rb + , Cs + ) picrate extraction method.

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