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Synthesis and Alignment of Iron Oxide Nanoparticles in a Regenerated Cellulose Film

✍ Scribed by Shilin Liu; Jinping Zhou; Lina Zhang; Jianguo Guan; Jianbo Wang


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
345 KB
Volume
27
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Summary: A polymer‐iron oxide nanocomposite film has been successfully synthesized by using a microporous regenerated cellulose film as template and aqueous ferrous chloride as precursor. The nanocomposite film was investigated with XRD, XPS, SEM, TEM, and VSM. The nanoparticles synthesized in situ were disk‐shaped with a mean diameter of β‰ˆ24 and thicknesses of 2.5–3.5 nm. For the first time, the nanodisks were well aligned in the cellulose matrix to form an ordered multibilayer structure by the shrinkage of the hybrid film while drying. The nanocomposite film displayed anisotropic magnetic properties as a result of the alignment of magnetic nanodisks. This work provides a novel and facile method for template synthesis of nanoparticles and aligned nanocomposites.

TEM image of the air‐dried nanocomposite film; slice perpendicular to the film plane.

magnified imageTEM image of the air‐dried nanocomposite film; slice perpendicular to the film plane.


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