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Synthesis and adduction of fully deprotected oligodeoxynucleotides containing 6-chloropurine

✍ Scribed by Hye-Young Kim; Lubomir Nechev; Liang Zhou; Pamela Tamura; Constance M. Harris; Thomas M. Harris

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 267 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01462-2

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✦ Synopsis

Fully deprotected oligodeoxynucleotides containing 6-chloropurine have been synthesized and used in solution phase reactions with amine nucleophiles to prepare oligonucleotides containing substituted adenine residues. 'This strategy was used for the preparation of a double-stranded oligonucleotide crosslinked by a 4-carbon tether between/v,, positions of deoxyadenosines in the two strands.

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