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Synthesis and absolute stereostructure of dinaphth[2,1- c: 1′,2′-e]oxepin-3-(5H)-one

✍ Scribed by Gerhard Bringmann; Thomas Hartung; Oliver Kröcher; Klaus-Peter Gulden; Joachim Lange; Hans Burzlaff

Book ID: 104204308
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 683 KB
Volume: 50
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)86996-9

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✦ Synopsis

The synthesis, enantiomer analysis, and configurational assignment of dinaphth[2,l-c:1',2'-e]oxepin-3-(5IT)-one, a seven-membered lactone-bridged chiral binaphthalene, is reported. The elucidation of the absolute configuration has been performed, independently by multiple scattering X-ray experiments and by circular dichroism (CD).

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