✦ LIBER ✦

Synthesis and 13C-N.m.r. spectra of methyl 2,3-diacetamido-2,3-dideoxy-α-d-hexopyranosides and 2,3-diacetamido-2,3-dideoxy-d-hexoses

✍ Scribed by Yuriy A. Knirel; Evgeniy V. Vinogradov; Nina A. Kocharova; Alexander S. Shashkov; Boris A. Dmitriev; Nikolay K. Kochetkov

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 612 KB
Volume: 122
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(83)88329-3

No coin nor oath required. For personal study only.

✦ Synopsis

ABSTRACf Previously unknown methyl 2,3-diacetamido-2,3-dideoxy-a-D-hexopyranosides having the gulo, allo, galacto, ido, and altro configurations, as well as 2,3-diacetamido-2,3-dideoxy-D-galactose, have been synthesised. 13C-N.m.r. data for all eight methyl 2,3-diacetamido-2,3-dideoxy-cu-D-hexopyranosides and for three 2,3-diacetamido-2,3-dideoxy-D-hexoses having the gluco, manno, and galacto configurations are reported. The regularity of changes in the spectra of 2,3diacetamido sugars, as compared with those of the parent hexoses, and the calculation of '"C-n.m.r.

spectra of their derivatives, using a method of additive corrections, are discussed.

📜 SIMILAR VOLUMES

Syntheses of methyl 2,6-diacetamido-2,3,

Syntheses of methyl 2,6-diacetamido-2,3,6-trideoxy-α-d-ribo-hexopyranoside (methyl di-N-acetyl-α-d-tobrosaminide) and methyl 2-acetamido-2,3,6-trideoxy-β-l-lyxo-hexopyranoside

✍ Mohammed M. Abuaan; John S. Brimacombe; Leslie C.N. Tucker 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 612 KB

The title glycosides were synthesised from D-glUCOSe, via the common intermediate methyl 2-acetamido-4-O-benzoyld-bromo-2,3,6-trideoxy-a-D-ribohexopyranoside . \*To whom enquiries should be addressed. \*\*The overall efficiency of this procedure can be improved by using a phase-transfer process' in

ChemInform Abstract: Stereoselective Pre

ChemInform Abstract: Stereoselective Preparation of 2,3-Dideoxy-3-C- [(α-D-Galactopyranosyl)methyl]-D-arabino-hexopyranose and 2,3-Dideoxy-3-C- [(α-D-Galactopyranosyl)methyl]-L-arabino-hexopyranose.

✍ Kamil Parkan; Ondrej Vich; Hana Dvorakova; Ladislav Kniezo 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 43 KB 👁 1 views

Synthesis of methyl [2-13C-2,2-d2]- and

Synthesis of methyl [2-13C-2,2-d2]- and [3-13C-3,3-d2]tetracosanoate

✍ J. George Pomonis; Heldur Hakk 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 French ⚖ 331 KB

Synthesis of 1-(3-azido-2,3-dideoxy-β-d-

Synthesis of 1-(3-azido-2,3-dideoxy-β-d-allofuranosyl)thymine, 1-(2,3-dideoxy-β-d-allofuranosyl)thymine, and 1-(2,3-dideoxy-β-d-erythro-hex-2-enofuranosyl)thymine

✍ Hubert Hřebabecký; Antonín Holý 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 598 KB

1-(2-O-Acetyl-3,5,6-tri-O-benzoyl-beta-D-glucofuranosyl)thymine (1) was converted into the 2,2'-anhydro derivative 4 by selective deacetylation, mesylation, and treatment with 1,8-diazabicyclo[5.4.0]undec-7-ene. Cleavage of the 2,2'-anhydro ring in 4 with hydrogen bromide or hydrogen chloride led to

ChemInform Abstract: Synthesis and Antiv

ChemInform Abstract: Synthesis and Antiviral Evaluation of α-D-2′-3′-Didehydro-2′,3′-dideoxy-3′-C-hydroxymethyl Nucleosides.

✍ Kohei Yamada; Hiroyuki Hayakawa; Shinji Sakata; Noriyuki Ashida; Yuichi Yoshimur 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Synthesis of 2,5-dideoxy-2-C-methyl-d-ar

Synthesis of 2,5-dideoxy-2-C-methyl-d-arabinose derivatives from methyl 2,3-anhydro-5-deoxy-α-d-ribofuranoside

✍ Hiroshi Yamamoto; Hiroshi Sasaki; Saburo Inokawa 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 553 KB