Syntheses, structures and properties of two Keggin polyoxometalates [H5PCo(4,4′-bipy)Mo11O39][H3PMo12O40]·3.75(4,4′-bipy)·1.5H2O and [H3PMo12O40]·2(4,4′-bipy)·1.5H2O

[ε-PMo12O36(OH)4{La(H2O)4}4]5+: The Firs

[ε-PMo12O36(OH)4{La(H2O)4}4]5+: The First ε-PMo12O40 Keggin Ion and Its Association with the Two-Electron-Reduced α-PMo12O40 Isomer

✍ Pierre Mialane; Anne Dolbecq; Laurent Lisnard; Alain Mallard; Jérôme Marrot; Fra 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB 👁 1 views

Polyoxometalates, often considered as soluble metal oxides, have long attracted interest because of their large field of applications, especially in the domain of heterogeneous catalysis. [1] The famous Keggin ion [a-PMo 12 O 40 ] 3À was isolated nearly 200 years ago. Isomerization formally results

[ε-PMo12O36(OH)4{La(H2O)4}4]5+: The Firs

[ε-PMo12O36(OH)4{La(H2O)4}4]5+: The First ε-PMo12O40 Keggin Ion and Its Association with the Two-Electron-Reduced α-PMo12O40 Isomer

✍ Pierre Mialane; Anne Dolbecq; Laurent Lisnard; Alain Mallard; Jérôme Marrot; Fra 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 144 KB 👁 1 views

Polyoxometalates, often considered as soluble metal oxides, have long attracted interest because of their large field of applications, especially in the domain of heterogeneous catalysis. [1] The famous Keggin ion [a-PMo 12 O 40 ] 3À was isolated nearly 200 years ago. Isomerization formally results

[ε-PMo12O36(OH)4{La (H2O)4}4]5+: The Fir

[ε-PMo12O36(OH)4{La (H2O)4}4]5+: The First ε-PMo12O40 Keggin Ion and Its Association with the Two-Electron-Reduced α-PMo12O40 Isomer.

✍ Pierre Mialane; Anne Dolbecq; Laurent Lisnard; Alain Mallard; Jerome Marrot; Fra 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 41 KB 👁 1 views

ChemInform Abstract: Two Novel Keggin Tu

ChemInform Abstract: Two Novel Keggin Tungstocobaltates Grafted by CobaltII Complex Group(s): K[Co(phen)2(H2O)]2 [HCoW12O40]×2H2O and [Co(2,2′-bipy)3]1.5{ [Co(2,2′-bipy)2(H2O)] [HCoW12O40]}×0.5H2O.

✍ Jingquan Sha; Jun Peng; Jing Chen; Hongsheng Liu; Aixiang Tian; Pengpeng Zhang 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 30 KB 👁 1 views

Oxomolybdenum(V) polyanion clusters. Hyd

Oxomolybdenum(V) polyanion clusters. Hydrothermal syntheses and structures of (NH4)5Na4{Na[Mo6O12(OH)3(O3PC6H5)4)]2}·6H2O (C6H5CH2NMe3)4K4{K2[Mo6O12(OH)3(O3PC6H5)4]2}·10H2O and their relationship to the binuclear (Et4N)[Mo2O4Cl3(H2O)3]·5H2O

✍ M.Ishaque Khan; Qin Chen; Jon Zubieta 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 973 KB

A Novel One-dimensional Reduced Molybden

A Novel One-dimensional Reduced Molybdenum(V) Decorated with Nickel Coordination Cations:Ni[Mo6O12(OH)3(PO4)(HPO4)3]2[Ni(H2O)2][Ni(H2O)(bipy)2]4·5H2O

✍ Hong-Xu GUO; Qing-Hua WANG; Chen CHEN; Min LIANG; Ling CHEN 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 189 KB 👁 1 views

A novel molybdenum(V) phosphate decorated with nickel complex cations, Ni[Mo 6 O 12 (OH) bipy＝2,2'-bipyridyl), has been hydrothermally synthesized and characterized by IR, TGA and single-crystal X-ray diffraction. Two {Mo 6 P 4 } clusters are linked via one Ni cation to form a Ni[Mo 6 P 4 ] 2 dimer