Three novel Cd(II)/Zn(II) compounds, [Cd 2 (poda) 2 (phen) 3 (H 2 O)] n ΓnEtOHΓ3nH 2 O(1), [Zn(poda) 2 (bpy) (H 2 O)] n (2) and [Zn(Hpoda) 2 (bpy)](3) (H 2 poda = 1,2-phenylenediacetic acid, phen = 1,10-phenanthroline, bpy = 2,2 0 -bipyridyl), have been synthesized and characterized by IR, TG, fluor
Syntheses, structures and luminescent properties of chain-like Zn(II) and Cd(II) complexes of 1,3-phenylenediacetate ligand
β Scribed by You-Fu Zhou; Rui-Hu Wang; Ben-Lai Wu; Rong Cao; Mao-Chun Hong
- Publisher
- Elsevier Science
- Year
- 2004
- Tongue
- English
- Weight
- 296 KB
- Volume
- 697
- Category
- Article
- ISSN
- 0022-2860
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## Abstract The dinuclear copper(II) complexes {[Cu~2~(1,3βtpbd)(H~2~O)(OAc)~2~](ClO~4~)~2~}~0.23~{[Cu~2~(1,3βtpbd)(H~2~O)~2~(OAc)](ClO~4~)~3~}~0.77~Β·0.77H~2~O (1), [Cu~2~(1,3βtpbd)(H~2~O)~2~(OAc)~2~](ClO~4~)~2~Β·2H~2~O (2), and the tetranuclear copper(II) complex [Cu~4~(1,3βtpbd)~2~(H~2~O)~2~(SO~4~
We synthesized a new organo-diphosphonic acid ligand H 2 O 3 PCH(Ph)NH(CH 2 ) 2 NH(Ph)CHPO 3 H 2 [ethane-1,2-diamino-N,N 0 -bis(benzyl phosphonic)acid, H 4 edbbp] and its two complexes The complexes 1-2 were structurally characterized by means of X-ray single crystal diffraction. The central ion (M